Byungil Hwang1 3 Wonsik Kim1 Jaemin Kim1 Subin Lee2 Seoyeon Lim1 Sangmin Kim1 Sangho Oh2 Seunghwa Ryu1 Seung Min Han1

1, Korea Advanced Institute of Science and Technology, Daejeon, , Korea (the Republic of)
3, BASF Electronics Materials R&D, Suwon, , Korea (the Republic of)
2, Sungkyunkwan University, Suwon, , Korea (the Republic of)

Nanoscale metal-graphene nanolayered composite is known to have ultra high strength due to its ability to effectively block dislocations from penetrating through the metal/graphene interface. The same graphene interface can simultaneously serve as an barrier interface for deflecting the fatigue cracks that are generated under cyclic bendings. Cu-graphene composite with repeat layer spacing of 100 nm was tested for bending fatigue at 1.6% and 3.1% strain up to 1,000,000 cycles that indicated ~5 times enhancement in robustness against fatigue induced damage in comparison to the conventional Cu only thin film. Fatigue induced cracks that are generated within the Cu layer were stopped by the graphene interface, which was confirmed using transmission electron microscopy images acquired ex-situ as well as during in-situ tensile strain testing. Molecular dynamics simulations for uniaxial tension of Cu/Gr showed limited accumulation of dislocations at the film/substrate interface, which makes the fatigue induced crack formation and propagation through thickness of the film difficult in this materials system.